Gamma-induced interconnected networks in microporous activated carbons from palm petiole under NaNO3 oxidizing environment towards high-performance electric double layer capacitors (EDLCs)
Nurulsafeelanaria Benwannamas, Tanagorn Sangtawesin, Murat Yılmaz, Kotchaphan Kanjana
Abstract
Abstract Activated carbons (ACs) were developed from palm petiole via a new eco-friendly method composed of highly diluted H 2 SO 4 hydrothermal carbonization and low-concentration KOH-activating pyrolysis followed by gamma-induced surface modification under NaNO 3 oxidizing environment. The prepared graphitic carbons were subsequently used as an active material for supercapacitor electrodes. The physiochemical properties of the ACs were characterized using field emission scanning electron microscope–energy dispersive X-ray spectroscopy, N 2 adsorption/desorption isotherms with Brunauer–Emmett–Teller surface area analysis, Fourier transform infrared spectroscopy, X-ray diffraction and Raman spectroscopy. The electrochemical performance of the fabricated electrodes was investigated by cyclic voltammetry, galvanostatic charge–discharge and electrochemical impedance spectroscopy. Even treated with extremely low H 2 SO 4 concentration and small KOH:hydrochar ratio, the maximum S BET of 1365 m 2 g −1 for an AC was obtained after gamma irradiation. This was attributed to radiation-induced interconnected network formation generating micropores within the material structure. The supercapacitor electrodes exhibited electric double-layer capacitance giving the highest specific capacitance of 309 F g −1 as well as excellent cycle stability within 10,000 cycles. The promising results strongly ensure high possibility of the eco-friendly method application in supercapacitor material production.