Solid organic-coated ammonium sulfate particles at high relative humidity in the summertime Arctic atmosphere
Rachel M. Kirpes, Ziying Lei, Matthew Fraund, Matthew J. Gunsch, Nathaniel W. May, T. E. Barrett, Claire E. Moffett, Andrew J. Schauer, Becky Alexander, Lucia M. Upchurch, Swarup China, Patricia K. Quinn, Ryan C. Moffet, Alexander Laskin, Rebecca J. Sheesley, Kerri A. Pratt, Andrew P. Ault
Abstract
SignificancePhysical and chemical properties of individual atmospheric particles determine their climate impacts. Hygroscopic inorganic salt particles mixed with trace amounts of organic material are predicted to be liquid under typical tropospheric conditions in the summertime Arctic. Yet, we unexpectedly observed a significant concentration of solid particles composed of ammonium sulfate with an organic coating under conditions of high relative humidity and low temperature. These particle properties are consistent with marine biogenic-derived new particle formation and growth, with particle collision hypothesized to result in the solid phase. This particle source is predicted to have increasing relevance in the context of declining Arctic sea ice and increasing open water, with impacts on clouds, and therefore climate.