Homochiral <i>versus</i> racemic polymorphs of spin-crossover iron(<scp>ii</scp>) complexes with reversible LIESST effect
Tingting Ma, Xiaopeng Sun, Zi‐Shuo Yao, Jun Tao
Abstract
Homochiral and racemic polymorphs show different spin-crossover behaviours due to different intermolecular interactions, and reversible LIESST effects can be realized on homochiral complexes.
Topics & Concepts
Spin crossoverIntermolecular forceChemistryCrystallographyCrossoverStereochemistryMoleculeOrganic chemistryComputer scienceArtificial intelligenceMagnetism in coordination complexesLanthanide and Transition Metal ComplexesMetal-Catalyzed Oxygenation Mechanisms