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Efficiency, mechanism and application prospect of ammonium adsorption and desorption over a sodium-acetate-modified synthetic zeolite

Heng-Deng Zhou, Chu‐Ya Wang, Qi Wang, Bo-Xing Xu, Guangcan Zhu

2024RSC Advances20 citationsDOIOpen Access PDF

Abstract

, and the adsorption process followed the Langmuir isotherm model and pseudo-second-order kinetics model. The adsorption and desorption of ammonium were controlled by ion exchange, pore diffusion, and electrostatic attraction processes. Ion exchange was responsible for 77.90% of the adsorption process and 80.16% of the desorption process. The MSZ was capable of continuously removing large amounts of ammonium from wastewater through fixed bed adsorption. After 5 regeneration cycles, MSZ still maintained 75% adsorption characteristics for ammonium. Using MSZ adsorbed with ammonium as a soil amendment increased the germination rate of mung beans by 10%. Furthermore, it also increased the stem length, root length, and fresh weight by 20-30%. These findings suggest that MSZ provides a promising application prospect to mitigate ammonium pollution and recycle ammonium resources.

Topics & Concepts

ZeoliteAdsorptionDesorptionIon exchangeChemistryAmmonium acetateInorganic chemistryAmmoniumSodiumPotassiumIonChemical engineeringNuclear chemistryOrganic chemistryCatalysisEngineeringHigh-performance liquid chromatographyAdsorption and biosorption for pollutant removalPhosphorus and nutrient managementAmmonia Synthesis and Nitrogen Reduction
Efficiency, mechanism and application prospect of ammonium adsorption and desorption over a sodium-acetate-modified synthetic zeolite | Litcius