Separation of <i>p</i>-Xylene from C8 Alkylaromatics by Nonporous Adaptive Crystals of Leggero Pillar[4]arene[1]quinone
Ge Zhang, Kun Zhang, Xin‐Yue Lou, Xin Li, Chun-Li Song, Weiwei Huan, Ying‐Wei Yang
Abstract
The separation and purification of C8 aromatics under nonthermal conditions remain a significant challenge in the chemical industry. Here, we report a new leggero pillararene containing one benzoquinone unit, namely, leggero pillar[4]arene[1]quinone ( P[4]Q[1]L ), which exhibits excellent guest sorting ability and vapochromic properties. Nonporous adaptive crystals (NACs) of P[4]Q[1]L can adsorb p -xylene from equal volume mixtures of C8 aromatics with high purity (97.5%), along with a color change from red to black. Single-crystal structures and powder X-ray diffraction data reveal that the high selectivity is attributed to the fact that p -xylene can trigger the structural rearrangement of P[4]Q[1]L NACs and form the corresponding host–guest assembly in the solid state. Moreover, P[4]Q[1]L NACs material is highly recyclable, because of the reversible transformation between guest-free and guest-loaded structures.