Ion Mobility Mass Spectrometry Uncovers Guest‐Induced Distortions in a Supramolecular Organometallic Metallosquare
Cristian Vicent, Victor Martínez‐Agramunt, Viraj Gandhi, Carlos Larriba‐Andaluz, Dmitry G. Gusev, Eduardo Peris
Abstract
Abstract The encapsulation of the tetracationic palladium metallosquare with four pyrene‐bis‐imidazolylidene ligands [ 1 ] 4+ with a series of organic molecules was studied by Electrospray ionization Travelling Wave Ion‐Mobility Mass Spectrometry (ESI TWIM‐MS). The method allowed to determine the Collision Cross Sections (CCSs), which were used to assess the size changes experienced by the host upon encapsulation of the guest molecules. When fullerenes were used as guests, the host is expanded ΔCCS 13 Å 2 and 23 Å 2 , for C 60 or C 70 , respectively. The metallorectangle [ 1 ] 4+ was also used for the encapsulation of a series of polycyclic aromatic hydrocarbons (PAHs) and naphthalenetetracarboxylic diimide (NTCDI), to form complexes of formula [(NTCDI) 2 (PAH)@ 1 ] 4+ . For these host:guest adducts, the ESI IM‐MS studies revealed that [ 1 ] 4+ is expanded by 47–49 Å 2 .. The energy‐minimized structures of [ 1 ] 4+ , [C 60 @ 1 ] 4+ , [C 70 @ 1 ] 4+ , [(NTCDI) 2 (corannulene)@ 1 ] 4+ in the gas phase were obtained by DFT calculations.Introduction