The surprising effects of sulfur: achieving long excited-state lifetimes in heteroleptic copper(<scp>i</scp>) emitters
Isaak Nohara, Christina Wegeberg, M. Devereux, Alessandro Prescimone, Catherine E. Housecroft, Edwin C. Constable
Abstract
The impact of the different chalcogens on the photophysical properties of [Cu(phen)(P^P)] + complexes in which phen has MeO or MeS groups in the 2,9-, 3,8- or 4,7-positions is described.
Topics & Concepts
ChalcogenCopperSulfurExcited stateMaterials sciencePhotochemistryCrystallographyChemistryMetallurgyAtomic physicsPhysicsMetal complexes synthesis and propertiesMagnetism in coordination complexesOrganometallic Complex Synthesis and Catalysis