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Structural properties of Co <sub>x</sub> Cu <sub>1−x</sub> Fe <sub>2</sub> O <sub>4</sub> solid solution <sup>**</sup>

Natheer B. Mahmood, Farqad R. Saeed, Kadhim R. Gbashi, Ali Hamodi, Zahraa M. Jaffar

2021Journal of the Mechanical Behavior of Materials25 citationsDOIOpen Access PDF

Abstract

Abstract Crystallography information files (CIF) were designed formed Co x Cu 1−x Fe 2 O 4 solid solution with the substitution factor x=0 to 1 with an increment of 0.1 depending on Vegard's law by using crystallography software. The effect of the substitution factor has been studied on some parameters and properties of the Co-Cu ferrite system, such as the effect of substitution factor on the lattice parameter, the volume of unit cell, and the density of the unit cell. Also, XRD patterns were estimated by crystallography software depending on the mathematical models of XRD. The XRD results showed a slight shift in the peak position varying with the substitution factor, these are due to the change in lattice parameter caused by the substitution of ions with different ionic radii. XRD also showed an increment in peak intensity varying with the substitution factor, that's due to an increase in the concentration of Cu which led to an increase in the density of electrons.

Topics & Concepts

Ionic radiusSolid solutionCrystallographySubstitution (logic)Materials scienceLattice constantX-ray crystallographyFerrite (magnet)Crystal structureLattice (music)Structure factorAnalytical Chemistry (journal)DiffractionIonChemistryPhysicsMetallurgyOpticsProgramming languageChromatographyOrganic chemistryComposite materialComputer scienceAcousticsMagnetic Properties and Synthesis of FerritesIron oxide chemistry and applicationsMultiferroics and related materials
Structural properties of Co <sub>x</sub> Cu <sub>1−x</sub> Fe <sub>2</sub> O <sub>4</sub> solid solution <sup>**</sup> | Litcius