Selective functionalization of benzylic C–H bonds of two different benzylic ethers by bowl-shaped <i>N</i>-hydroxyimide derivatives as efficient organoradical catalysts
Terumasa Kato, Keiji Maruoka
Abstract
-hydroxyimide organoradical catalysts with diethyl azodicarboxylate. The synthetic utility of this approach is demonstrated by the subsequent transformation of the amination products into the corresponding aldehydes and alkylhydrazines.
Topics & Concepts
AminationChemistryCatalysisSurface modificationEtherDiethyl azodicarboxylateOrganic chemistryDiethyl etherTransformation (genetics)Combinatorial chemistryMedicinal chemistryTriphenylphosphinePhysical chemistryBiochemistryGeneSynthesis and Catalytic ReactionsCatalytic C–H Functionalization MethodsRadical Photochemical Reactions