Fast Thermal Quenching on the Ferroelectric Al:HfO2 Thin Film with Record Polarization Density and Flash Memory Application
Bon‐Cheol Ku, Seonjun Choi, Yunheub Song, Changhwan Choi
Abstract
We have investigated the effects of post cooling process with chamber cooling, air cooling and fast quenching in DI water on the ferroelectric (FE) characteristics of Al-doped Hf0 <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> (Al:HfO <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> ) thin films and demonstrated their potential flash memory applications. Compared with other cooling processes, using fast quenching after annealing we achieved the drastic increase of remnant polarization (Pr) and coercive electric field (Ec). The highest 2Pr and 2Ec are ~ 100μC/cm <sup xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sup> and ~9.5 MV/cm, respectively, the highest records among HfO <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> -based FE reported so far. These improvements are attributed to induce higher stress/strain within A1:HfO <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> thin film, leading to stable orthorhombic phase (o-phase). Program/erase up to 10 <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">6</sub> cycles and 10 years retention characteristics are also evaluated for the potential flash memory application. Our simulation with experimental data indicates that P <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">r</sub> and E <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">c</sub> significantly can influence on the memory window and multi-bit states, which can be tuned by our proposed quenching process.