Experimental study on cobalt adsorption by bone powder modified with poly Pyrrole and polyethylene glycol
Javad Yarmohammadi Jamaloi, Majid Riahi Samani, Davood Toghraie
Abstract
• Efficacy of bone powder/poly Pyrrole composites as a sustainable method for adsorbing heavy metals. • The synthesis conditions affect the adsorption capacity of the composites for cobalt removal. • Highest cobalt removal percentage of 68.06 % was achieved with a polyethylene glycol concentration of 3 g/L. • The choice of solvent influences both the morphology and adsorption capacity of the composites. • Maximum cobalt removal occurs at an equilibrium time of 30 mins Heavy metals, including cobalt, are significant pollutants in water and wastewater. This study investigates the use of bone powder and a bone powder/poly-pyrrole composite for the removal of cobalt from aqueous solutions through batch experiments. The results indicate that the highest cobalt removal percentage achieved was 68.06 %, while the lowest was 59.80 %. These variations were attributed to the addition of polyethylene glycol and polyvinyl alcohol at concentrations of 3 g/L and 1 g/L, respectively, during the synthesis of the bone powder/poly-pyrrole composite. The influence of solvent type on the removal efficiency revealed that the highest removal percentage (57.07 %) was attained using butanol and water solvents in the presence of 3 g/L PEG. Increasing the initial pH of the solution enhanced the adsorption capacity, with maximum cobalt adsorption observed at pH 7. The optimal composite adsorbent demonstrated an equilibrium time of 30 mins. Additionally, the pseudo-second-order kinetic model was identified as the best fit for cobalt adsorption, based on the correlation coefficient (R²). The removal efficiency increased to 92.18 % when the adsorbent dose was raised from 2 g/L to 8 g/L, with a corresponding increase in cobalt removal. The experimental data conformed to the Langmuir isotherm model, as indicated by the adsorption isotherm results.