Optimization of optical properties and radiation shielding efficiency in BaO-PbO2-B2O3-Dy2O3 glass systems
M.I. Sayyed, Shrikant Biradar, Taha A. Hanafy, Y. Maghrbi, Mohammad Rashed Iqbal Faruque, Sabirin Abdullah, Sabina Yasmin
Abstract
This work explores the optical characteristics and radiation shielding efficiency of 21BaO-(14+3x) PbO 2 -(65-4x) B 2 O 3 -yDy 2 O 3 ; x = y = 0, 1, 2 and 3 mol% glass systems synthesized through the conventional method called melt-quenching. UV–Vis spectroscopy revealed that the incorporation of PbO 2 and Dy 3+ ions influenced optical transitions, leading to an increased cut-off wavelength, a reduction in energy band gaps from 2.424 to 2.319 eV for indirect transitions, and rise in the refractive index from 2.563 to 2.611. These findings indicate structural changes within the glass network, particularly the production of non-bridging oxygen atoms (NBOs). Radiation shielding features, computed with Phy-X software, revealed that the glass with 23 mol% PbO 2 and 3 mol% Dy 2 O 3 (Pb23Dy3) had the highest mass and linear attenuation coefficients (MAC and LAC), lowest half-value layer (HVL), Tenth value layer (TVL) and superior radiation protection efficiency (RPE) across a broad energy spectrum (0.015–15 MeV). These results suggest that adding PbO 2 and Dy 2 O 3 greatly improves the glass's optical performance and radiation attenuation capability, making it a highly effective option for advanced radiation protection uses. • 21BaO-(14+3x) PbO 2 -(65-4x) B 2 O 3 -yDy 2 O 3 glasses were prepared. • The density elevated from 4.11 to 4.89 g/cm 3 as the dopant contents increased. • The incorporation of PbO 2 and Dy 3+ ions influenced optical transitions. • The glass with 23 mol% PbO 2 and 3 mol% Dy 2 O 3 (Pb23Dy3) had the highest MAC.