Alkynyl-Stabilized Superatomic Silver Clusters Showing Circularly Polarized Luminescence
Miaomiao Zhang, Xi‐Yan Dong, Zhao‐Yang Wang, Xi‐Ming Luo, Jia‐Hong Huang, Shuang‐Quan Zang, Thomas C. W. Mak
Abstract
axis) and 1S orbitals. This work opens a new avenue for CPL-active metal nanoclusters by utilizing chiral alkynyl ligands and enlightens the chirality transfer from chiral protecting ligands to superatomic states in metal clusters.
Topics & Concepts
Chirality (physics)ChemistryNanoclustersLuminescenceExcited stateAtomic orbitalEnantiomerCircular polarizationPolyoxometalateQuantum yieldAxial chiralityMetalPhotochemistryCrystallographyStereochemistrySymmetry breakingAtomic physicsEnantioselective synthesisOptoelectronicsOrganic chemistryOpticsChiral symmetry breakingPhysicsCatalysisQuantum mechanicsNambu–Jona-Lasinio modelMicrostripElectronFluorescenceNanocluster Synthesis and ApplicationsRandom Matrices and ApplicationsGold and Silver Nanoparticles Synthesis and Applications