Diffusion-aware voltage source: An equivalent circuit network to resolve lithium concentration gradients in active particles
Mingzhao Zhuo, Niall Kirkaldy, Thomas Maull, Timothy Engstrom, Gregory J. Offer, Monica Marinescu
Abstract
Traditional equivalent circuit models (ECMs) have difficulties in estimating battery internal states due to the lack of relevant physics, such as the lithium diffusion in active particles. Here we configure a circuit network to describe the lithium diffusion and define it as a new high-level circuit element called diffusion-aware voltage source. The circuit representation is proven equivalent to the discretized diffusion equation. The new voltage source gives the electrode potential as a function of the surface concentration and thus automatically incorporates the diffusion overpotential. We show that an ECM with the proposed diffusion-aware voltage sources (called “shell ECM”) can reproduce the single particle model simulation results, making it a trustworthy easy-to-implement substitute. Furthermore, the simplest shell ECM consisting of a single diffusion-aware voltage source and a resistor is validated against experimental constant-current discharges at various rates. The diffusion-aware voltage source can be used to measure diffusivity by fitting the diffusion resistance against experimental data. The viability of the shell ECM for onboard usage is confirmed by implementation into a battery management system of WAE Technologies. By tracking the internal concentration states, the shell ECM demonstrates robustness to dynamic applied-current profiles.