A tetraphenylborate-based anionic metal–organic framework as a versatile solid electrolyte for fast Li<sup>+</sup>, Na<sup>+</sup>, K<sup>+</sup>, Mg<sup>2+</sup>, Ca<sup>2+</sup>, and Zn<sup>2+</sup> transportation
Qingchun Xia, Kaixin Han, Xuxiao Ma, Pengtao Qiu, Zhiyong Li, Xuenian Chen
Abstract
, our anionic MOF is also available for other types of solid electrolytes with the corresponding conductivities all above that of the functional battery electrolyte. Our work provided a convenient and tunable route to prepare conducting MOFs for alkali metal ions, alkaline earth metal ions, and other possible metal cations of interest, which could be used in solid-state electrolytic devices in the future.
Topics & Concepts
TetraphenylborateChemistryInorganic chemistryElectrolyteMetalRadiochemistryNuclear chemistryPhysical chemistryIonOrganic chemistryElectrodeAdvanced Battery Materials and TechnologiesMetal-Organic Frameworks: Synthesis and ApplicationsAdvancements in Battery Materials