Tertiary arsine ligands for the Stille coupling reaction
Akane Chishiro, Masafumi Konishi, Ryoto Inaba, Takashi Yumura, Hiroaki Imoto, Kensuke Naka
Abstract
Tertiary arsenic ligands were utilized for the Stille coupling reaction to elucidate the relationship between ligand structure and catalytic activity. Tri( p -anisyl)arsine showed the highest yield, and the mechanism was analysed by DFT calculations.
Topics & Concepts
Stille reactionArsineChemistryCoupling reactionTriphenylarsineLigand (biochemistry)Computational chemistryPhotochemistryOrganic chemistryCatalysisPhosphineReceptorTriphenylphosphineBiochemistryCatalytic Cross-Coupling ReactionsCatalytic C–H Functionalization MethodsOxidative Organic Chemistry Reactions