Oxygen Vacancy‐Controlled CuO<sub>x</sub>/N,Se Co‐Doped Porous Carbon via Plasma‐Treatment for Enhanced Electro‐Reduction of Nitrate to Green Ammonia
Junbeom Maeng, Daehee Jang, Jungseub Ha, Junhyuk Ji, Jaehyun Heo, Yeji Park, Su-Bin Kim, Won Bae Kim
Abstract
Abstract The electrochemical nitrate reduction reaction (NO 3 RR) is of significance in regards of environmentally friendly issues and green ammonia production. However, relatively low performance with a competitive hydrogen evolution reaction (HER) is a challenge to overcome for the NO 3 RR. In this study, oxygen vacancy‐controlled copper oxide (CuO x ) catalysts through a plasma treatment are successfully prepared and supported on high surface area porous carbon that are co‐doped with N, Se species for its enhanced electrochemical properties. The oxygen vacancy‐increased CuO x catalyst supported on the N,Se co‐doped porous carbon (CuO x ‐H/NSePC) exhibited the highest NO 3 RR performance with faradaic efficiency (FE) of 87.2% and yield of 7.9 mg cm −2 h −1 for the ammonia production, representing significant enhancements of FE and ammonia yield as compared to the un‐doped or the oxygen vacancy‐decreased catalysts. This high performance should be attributed to a significant increase in the catalytic active sites with facilitated energetics from strategies of doping the catalytic materials and weakening the N─O bonding strength for the adsorption of NO 3 − ions on the modulated oxygen vacancies. This results show a promise that co‐doping of heteroatoms and regulating of oxygen vacancies can be key factors for performance enhancement, suggesting new guidelines for effective catalyst design of NO 3 RR.