Reshaping the Module: The Path to Comprehensive Photovoltaic Panel Recycling
Patrick Isherwood
Abstract
The market for photovoltaic modules is expanding rapidly, with more than 500 GW installed capacity. Consequently, there is an urgent need to prepare for the comprehensive recycling of end-of-life solar modules. Crystalline silicon remains the primary photovoltaic technology, with CdTe and CIGS taking up much of the remaining market. Modules can be separated by crushing or cutting, or by thermal or solvent-based delamination. Separation and extraction of semiconductor materials can be achieved through manual, mechanical, wet or dry chemical means, or a combination. Crystalline silicon modules are currently recycled through crushing and mechanical separation, but procedures do exist for extraction and processing of intact wafers or wafer pieces. Use of these processes could lead to the recovery of higher grades of silicon. CdTe panels are mostly recycled using a chemical leaching process, with the metals recovered from the leachate. CIGS can be recycled through oxidative removal of selenium and thermochemical recovery of the metals, or by electrochemical or hydrometallurgical means. A remaining area of concern is recycling of the polymeric encapsulant and backsheet materials. There is a move away from the use of fluorinated backsheet polymers which may allow for improved recycling, but further research is required to identify materials which can be recycled readily whilst also being able to withstand outdoor environments for multi-decadal timespans.