Photocatalytic C(sp<sup>3</sup>)–H thiolation by a double S<sub>H</sub>2 strategy using thiosulfonates
Nobukazu Taniguchi, Mamoru Hyodo, Lin‐Wei Pan, Ilhyong Ryu
Abstract
Site-selective thiolation of C(sp 3 )–H bonds was achieved by a double S H 2 strategy, for which thiosulfonates were used as a thiolating reagent and decatungstate anion as a photocatalyst.
Topics & Concepts
ReagentChemistryDouble bondPhotocatalysisIonPhotochemistryPolymer chemistryCatalysisOrganic chemistrySulfur-Based Synthesis TechniquesCatalytic C–H Functionalization MethodsChemical Synthesis and Reactions