Mn(<scp>iii</scp>)–porphyrin catalysts for the cycloaddition of CO<sub>2</sub> with epoxides at atmospheric pressure: effects of Lewis acidity and ligand structure
Bruno N. Cabral, Jorge Luiz Sônego Milani, Alexandre Moreira Meireles, Dayse Carvalho da Silva Martins, Stephany Larissa da Silva Ribeiro, Júlio S. Rebouças, Cláudio Luis Donnici, Rafael Pavão das Chagas
Abstract
Mn(<sc>iii</sc>)–porphyrin catalysts with electron-withdrawing substituents were designed to uncover electronic and structural aspects in the cycloaddition of CO<sub>2</sub> with epoxides.
Topics & Concepts
ChemistryPorphyrinCatalysisAtmospheric pressureLigand (biochemistry)CycloadditionLewis acids and basesMedicinal chemistryOrganic chemistryReceptorBiochemistryGeologyOceanographyCarbon dioxide utilization in catalysisCO2 Reduction Techniques and CatalystsCatalysts for Methane Reforming