Screening Nanographene‐Mediated Inter(Porphyrin) Communication to Optimize Inter(Porphyrin–Fullerene) Forces
Philipp Haines, Ramandeep Kaur, Max Martin, Martin B. Minameyer, Stefan Frühwald, Simon Bönisch, Dominik Lungerich, Frank Hampel, Andreas Görling, Thomas Drewello, Norbert Jux, Dirk M. Guldi
Abstract
Abstract Multifunctional molecular materials comprising porphyrins and fullerenes have served as perfect prototypes to study key aspects of natural photosynthesis starting at light harvesting and energy transfer processes all the way to charge separation, charge shift, and charge recombination. Herein, hexa‐ peri ‐hexabenzocoronenes (HBCs) are explored, decorated with one, two, and six porphyrins at their peripheral positions, within the context of replicating key steps of photosynthesis. The major focus of the investigations is to screen inter(porphyrin) communications across the HBC platform as a function of the substitution pattern and to optimize the intermolecular forces with fullerenes. To this end, the ground‐ and excited‐state features are investigated in the absence of C 60 and C 70 by employing an arsenal of spectroscopic methods. Further insights into inter(porphyrin) communications come from time‐dependent density‐functional theory (TDDFT) calculations. In the presence of C 60 and C 70 , X‐ray crystallography, steady‐state and time‐resolved spectroscopy, and mass spectrometry corroborate exceptionally strong inter(porphyrin–fullerene) interactions in the solid, liquid, and gas phases. The experiments are backed‐up with DFT calculations of the geometrically optimized and energetically stable complex configuration.