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Preparation of MgTi2O5 nanoparticles for sonophotocatalytic degradation of triphenylmethane dyes

Thangavel Selvamani, Sambandam Anandan, Abdullah M. Asiri, P. Maruthamuthu, Muthupandian Ashokkumar

2021Ultrasonics Sonochemistry59 citationsDOIOpen Access PDF

Abstract

MgTi2O5 (magnesium dititanate) nanoparticles were prepared by a simple hydrothermal assisted post-annealing method and characterized with various analytical techniques. The catalytic properties (sonocatalytic, photocatalytic and sonophotocatalytic activity) were evaluated using the degradation of triphenylmethane dyes (crystal violet, basic fuchsin, and acid fuchsin). The sonophotocatalytic activity of MgTi2O5 nanoparticles towards crystal violet was found to be ~2.9 times higher than the photocatalytic activity and ~20 times higher than that of the sonocatalytic processes. In addition, the sonophotocatalytic efficiency of MgTi2O5 nanoparticles was found to be remarkable for the degradation of basic fuchsin (cationic dye) and acid fuchsin (anionic dye). The mechanism of these catalytic activities has been discussed in detail.

Topics & Concepts

Crystal violetPhotocatalysisCationic polymerizationTriphenylmethaneCatalysisDegradation (telecommunications)NanoparticleEosin YChemistryMaterials scienceChemical engineeringNanotechnologyOrganic chemistryTelecommunicationsMedicinePathologyEngineeringComputer scienceAdvanced Photocatalysis TechniquesTiO2 Photocatalysis and Solar CellsUltrasound and Cavitation Phenomena