Cavity-catalyzed hydrogen transfer dynamics in an entangled molecular ensemble under vibrational strong coupling
Eric W. Fischer, Peter Saalfrank
Abstract
Light-matter entanglement in a cavity-catalysed hydrogen transfer ensemble reaction model is studied, its relevance for thermal rate enhancement is discussed and entanglement-related deviations from reactive single-molecule models are analyzed.
Topics & Concepts
Hamiltonian (control theory)QuantumChemistryMolecular dynamicsQuantum entanglementCoupling (piping)Chemical physicsMoleculeMolecular vibrationPhysicsMolecular physicsQuantum mechanicsMaterials scienceMetallurgyMathematicsMathematical optimizationStrong Light-Matter InteractionsThermal Radiation and Cooling TechnologiesMechanical and Optical Resonators