Efficient oxidation of benzyl alcohol into benzaldehyde catalyzed by graphene oxide and reduced graphene oxide supported bimetallic Au–Sn catalysts
Lili Liu, Lili Liu, Xiaojing Zhou, Chunling Xin, Baoli Zhang, Guangman Zhang, Shanshan Li, Li Liu, Li Liu, Xi–Shi Tai
Abstract
as an oxidizing agent under moderate conditions. To obtain the optimal BzH yield, the experimental conditions and parameters, including the effects of the reaction time, temperature, pressure, and solvent type on BzOH oxidation, were optimized. Under optimal reaction conditions, bimetallic Au-Sn nanoparticles supported on GO (AuSn/GO-TS, 49.3%) produced a greater yield of BzH than the AuSn/rGO-TS catalysts (35.5%). The Au-Sn bimetallic catalysts were more active than the monometallic catalysts. AuSn/GO-TS and AuSn/rGO-TS prepared by the two-step immobilization method were more active than AuSn/GO-CoIM and AuSn/rGO-CoIM prepared by co-immobilization. In addition, the AuSn/GO-TS and AuSn/rGO-TS catalysts were easily separated from the mixture by centrifugation and reused at least four times without reducing the yield of BzH. These properties make Au-Sn bimetallic nanoparticles supported on GO and rGO particularly attractive for the environmentally friendly synthesis of benzaldehyde.