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Improved Thermophysical Properties of Developed Ternary Nitrate-Based Phase Change Material Incorporated with MXene as Novel Nanocomposites

Ilancheliyan Samylingam, Navid Aslfattahi, K. Kadirgama, M. Samykano, Lingenthiran Samylingam, R. Saidur

2021Energy Engineering12 citationsDOIOpen Access PDF

Abstract

In this study, nanocomposite of ternary nitrate molten salt induced with MXene is developed. LiNO3-NaNO3-KNO3 with wt% of 35:12:53 and 35:10:55 are produced and doped with MXene in the wt% of 0.2, 0.5, 1.0, and 1.5. FTIR result indicates the composites had no chemical reaction occurred during the preparation. UV-VIS analysis shows the absorption enhancement with respect to the concentration of MXene. Thermogravimetric analysis (TGA) was used to measure the thermal stability of the LiNO3-NaNO3-KNO3 induced with MXene. The ternary molten salts were stable at temperature range of 600–700°C. Thermal stability increases with the addition of MXene. 1.5 wt% of MXene doped with LiNO3-NaNO3-KNO3 with wt% 35:10:55 and 35:12:53, increases the thermal stability from 652.13°C to 731.49°C and from 679.82°C to 684.57°C, respectively. Using thermophysically enhanced molten salt will increase the efficiency of CSP.

Topics & Concepts

Thermogravimetric analysisThermal stabilityTernary operationNanocompositeMolten saltMaterials scienceSalt (chemistry)Thermal analysisTernary numeral systemFourier transform infrared spectroscopyAbsorption (acoustics)Phase (matter)Sodium nitrateChemical engineeringNitrateDopingNuclear chemistryChemistryThermalComposite materialMetallurgyOrganic chemistryThermodynamicsProgramming languageOptoelectronicsPhysicsEngineeringComputer sciencePhase Change Materials ResearchAdvanced Battery Materials and TechnologiesMXene and MAX Phase Materials
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