Mechanistic insights into carbamate formation from CO<sub>2</sub>and amines: the role of guanidine–CO<sub>2</sub>adducts
Jere K. Mannisto, Ljiljana Pavlovic, Tony Tiainen, Martin Nieger, Aleksi Sahari, Kathrin H. Hopmann, Timo Repo
Abstract
This work explores the reactivity of a reversible superbase–CO 2 zwitterion, which can be used as a stoichiometric source of CO 2 .
Topics & Concepts
ZwitterionGuanidineReactivity (psychology)ChemistryAdductCarbamateCatalysisSuperbaseStoichiometryCombinatorial chemistryMedicinal chemistryOrganic chemistryMoleculePathologyAlternative medicineMedicineCarbon dioxide utilization in catalysisCO2 Reduction Techniques and CatalystsAsymmetric Hydrogenation and Catalysis