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Oxygen-Deficient Engineering for Perovskite Oxides in the Application of AOPs: Regulation, Detection, and Reduction Mechanism

Jiayu Yu, Huanhuan Li, Naipeng Lin, Yishu Gong, Hu Jiang, Jiajia Chen, Yin Wang, Xiaodong Zhang

2023Catalysts54 citationsDOIOpen Access PDF

Abstract

A perovskite catalyst combined with various advanced oxidation processes (AOPs) to treat organic wastewater attracted extensive attention. The physical and chemical catalytic properties of perovskite were largely related to oxygen vacancies (OVs). In this paper, the recent advances in the regulation of OVs in perovskite for enhancing the functionality of the catalyst was reviewed, such as substitution, doping, heat treatment, wet-chemical redox reaction, exsolution, and etching. The techniques of detecting the OVs were also reviewed. An insight was provided into the OVs of perovskite and reduction mechanism in AOPs in this review, which is helpful for the reader to better understand the methods of regulating and detecting OVs in various AOPs.

Topics & Concepts

Perovskite (structure)RedoxCatalysisOxygenChemistryMechanism (biology)Materials scienceChemical engineeringNanotechnologyInorganic chemistryOrganic chemistryPhilosophyEpistemologyEngineeringAdvancements in Solid Oxide Fuel CellsElectronic and Structural Properties of OxidesPerovskite Materials and Applications