Unprecedented highly efficient photoluminescence in a phosphorescent Ag(<scp>i</scp>) coordination polymer
Haruka Yoshino, Masaki Saigo, Kiyoshi Miyata, Ken Onda, Jenny Pirillo, Yuh Hijikata, Wataru Kosaka, Hitoshi Miyasaka
Abstract
A novel Ag-based coordination polymer with a bright phosphorescence originating from metal–metal to ligand charge transfer was synthesized. The Ag⋯Ag-related emission path and structural rigidity resulted in outstanding luminescence efficiency.
Topics & Concepts
PhotoluminescencePhosphorescencePolymerChemistryMaterials sciencePhotochemistryChemical engineeringNanotechnologyOptoelectronicsFluorescenceOrganic chemistryPhysicsOpticsEngineeringMetal-Organic Frameworks: Synthesis and ApplicationsLuminescence and Fluorescent MaterialsPolyoxometalates: Synthesis and Applications