Efficient amine oxidation using metal–organic framework photocatalysts for aminoalkyl radical-mediated halogen-atom transfer
Xin Liu, Zhifen Guo, Yan Che, Xingbing Liu, Min Yu, Jiahuan Lv, Mengying Li, Hongzhu Xing, Peng Chen
Abstract
Efficient photooxidation of amines by visible-light-responsive metal–organic frameworks generating α-aminoalkyl radicals to achieve halogen-atom transfer (XAT) reactions of dehalogenation, hydroalkylation and polyfluoroarylation.
Topics & Concepts
HalogenRadicalChemistryHalogenationAmine gas treatingPhotochemistryMetalPhotoredox catalysisAtom (system on chip)Combinatorial chemistryCatalysisPhotocatalysisOrganic chemistryAlkylEmbedded systemComputer scienceMetal-Organic Frameworks: Synthesis and ApplicationsRadical Photochemical ReactionsSulfur-Based Synthesis Techniques