Dioxane promoted photochemical <i>O</i>-alkylation of 1,3-dicarbonyl compounds beyond carbene insertion into C–H and C–C bonds
Xinlong Zhou, Jingjing Jiang, Min Zhang, Qingqing Wu, Keyong Zhu, Dongjie Shi, Sensen Hou, Jingjing Zhao, Pan Li
Abstract
-alkylation of various 1,3-dicarbonyl compounds beyond previous carbene insertion into C-H and C-C bonds has been disclosed.
Topics & Concepts
CarbeneAlkylationChemistryMedicinal chemistryInsertion reactionPhotochemistryCatalysisOrganic chemistryCyclopropane Reaction MechanismsCatalytic C–H Functionalization MethodsOxidative Organic Chemistry Reactions