A sustainable C–H functionalization of indoles, pyrroles and furans under a blue LED with iodonium ylides
Saibal Sar, Ranajit Das, Dhiraj Barman, Pikaso Latua, Souvik Guha, Ludovic Gremaud, Subhabrata Sen
Abstract
Pyrrole and indole derivatives are functionalized with the dimethyl malonate derived phenyl iodonium ylide in the presence of a blue LED via C–H functionalization of the respective heterocycles in methanol to generate the desired compounds.
Topics & Concepts
ChemistrySurface modificationIndole testPyrroleMalonateMethanolYlideCombinatorial chemistryMedicinal chemistryOrganic chemistryPhysical chemistryCatalytic C–H Functionalization MethodsOxidative Organic Chemistry ReactionsSynthesis and Catalytic Reactions