Superconductivity arising from pressure-induced emergence of a Fermi surface in the kagome-lattice chalcogenide <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:msub><mml:mi>Rb</mml:mi><mml:mn>2</mml:mn></mml:msub><mml:msub><mml:mi>Pd</mml:mi><mml:mn>3</mml:mn></mml:msub><mml:msub><mml:mi>Se</mml:mi><mml:mn>4</mml:mn></mml:msub></mml:math>
Qing Li, Yuxiang Wu, Xinwei Fan, Yingjie Zhang, Xiyu Zhu, Zhengyan Zhu, Yiwen Li, Hai‐Hu Wen
Abstract
According to the Bardeen-Cooper-Schrieffer theory, superconductivity usually needs well-defined Fermi surface(s) with strong electron-phonon coupling and moderate quasiparticle density of states. A kagome lattice can host flat bands and topological Dirac bands; meanwhile, due to the parallel Fermi surfaces and saddle points, many interesting orders are expected. Here, we report the observation of superconductivity by pressurizing a kagome compound ${\mathrm{Rb}}_{2}{\mathrm{Pd}}_{3}{\mathrm{Se}}_{4}$ using a diamond-anvil-cell. The parent compound shows an insulating behavior; however, it gradually becomes metallic and turns to a superconducting state when high pressure is applied. High-pressure synchrotron measurements show that there is no structural transition occurring during this process. The density-functional-theory calculations illustrate that the insulating behavior of the parent phase is due to the crystalline field splitting of the partial $\mathrm{Pd}\text{\ensuremath{-}}4d\phantom{\rule{0.16em}{0ex}}{t}_{\text{2g}}$ bands and the Se-derivative $4p$ band. However, the threshold of metallicity and superconductivity are reached when the Lifshitz transition occurs, leading to the emergence of a tiny Fermi surface at the $\mathrm{\ensuremath{\Gamma}}$ point. Our results point to an unconventional superconductivity and shed light on understanding the electronic evolution of a kagome material.