Mechanochemical defect engineering of HKUST-1 and impact of the resulting defects on carbon dioxide sorption and catalytic cyclopropanation
Timothy Steenhaut, Nicolas Grégoire, Gabriella Barozzino‐Consiglio, Yaroslav Filinchuk, Sophie Hermans
Abstract
Defective HKUST-1 was prepared by salt- or liquid-assisted grinding with post-synthetic treatments with alcohols. The defects identified as free carboxylic acid groups or reduced Cu(<sc>i</sc>) sites influence strongly gas storage and catalytic properties.
Topics & Concepts
SorptionCatalysisCyclopropanationGrindingCarbon dioxideChemical engineeringSalt (chemistry)ChemistryCarboxylic acidCarbon fibersMaterials scienceOrganic chemistryMetallurgyComposite materialComposite numberAdsorptionEngineeringMetal-Organic Frameworks: Synthesis and ApplicationsCovalent Organic Framework ApplicationsCarbon dioxide utilization in catalysis