Review—Gassing Mechanisms in Lithium-ion Battery
Baptiste Salomez, Sylvie Grugeon, Michel Armand, Pierre Tran‐Van, Stéphane Laruelle
Abstract
This paper provides a holistic view of the different studies related to gassing in NMC/graphite lithium-ion batteries over the past couple of decades of scientific development. It underlines the difficulty of predicting the concentration and the proportion of gas released upon cycling and storage and to get a clear mechanistic insight into the reduction and oxidation pathways of electrolyte solvents, the thermal electrolyte degradation, as well as the reactions that involve secondary sources such as water, NMC surface species and cross-talk reactions. Though many relevant experiments such as operando gas analysis using isotope-labeled solvents or two-compartment cells have been conducted, they failed, for instance, to determine the exact mechanism leading to the generation of CO and CO 2 gas. Last but not least, this paper discusses different strategies that are currently proposed to reduce or eliminate gassing such as the use of electrolyte additives that enable singlet oxygen quenching or scavenging, NMC coatings that limit the contact with electrolyte and different lithium salts to prevent thermal electrolyte degradation.