Metal–metal cooperative bond activation by heterobimetallic alkyl, aryl, and acetylide Pt <sup>II</sup> /Cu <sup>I</sup> complexes
Shubham Deolka, Orestes Rivada‐Wheelaghan, Sandra L. Aristizábal, Robert R. Fayzullin, Shrinwantu Pal, Kyoko Nozaki, Eugene Khaskin, Julia R. Khusnutdinova
Abstract
anion and mild C-H bond cleavage of a terminal alkyne, which was not observed in the absence of an electrophilic Cu center. The DFT study indicates that the Cu center acts as a binding site for the alkyne substrate, while activating its terminal C-H bond.
Topics & Concepts
AcetylideChemistryMetalAlkylReactivity (psychology)ArylCenter (category theory)Medicinal chemistryOxidative additionStereochemistryCrystallographyCatalysisOrganic chemistryMedicineAlternative medicinePathologyCatalytic C–H Functionalization MethodsCatalytic Cross-Coupling ReactionsCatalytic Alkyne Reactions