Synthesis, structure and properties of a high-energy metal–organic framework fuel [Cu(MTZ)<sub>2</sub>(CTB)<sub>2</sub>]<sub><i>n</i></sub>
Haozheng Mei, Yiqiang Xu, Guorong Lei, Wenli Cao, Zhimin Li, Jianguo Zhang
Abstract
In this study, a novel high-energy metal–organic framework (MOF, [Cu(MTZ) 2 (CTB) 2 ] n ) was constructed based on the nitrogen-rich cyanotetrazolylborohydride (CTB) and 1-methyltriazole (MTZ) ligands, with Cu 2+ as the autocatalytic metal centers.
Topics & Concepts
ChemistryMetalMetal-organic frameworkNitrogenInorganic chemistryPhysical chemistryOrganic chemistryAdsorptionMetal-Organic Frameworks: Synthesis and ApplicationsEnergetic Materials and CombustionCrystallography and molecular interactions