Palladium-catalyzed intramolecular aerobic oxidative cross-coupling of BH/CH between <i>o</i>-carborane and arenes
Zhen Wang, Jiahui Yu, Jie Zhang, Dengsong Zhang, Zaozao Qiu, Zuowei Xie
Abstract
Efficient Pd-catalyzed regioselective intramolecular aerobic oxidative coupling of BH/CH has been achieved with the construction of a series of five-, six- and seven-membered rings, facilitating potential applications in carborane-based luminogens.
Topics & Concepts
Intramolecular forceCarboranePalladiumOxidative phosphorylationCatalysisChemistryMedicinal chemistryCoupling (piping)Combinatorial chemistryStereochemistryOrganic chemistryMaterials scienceBiochemistryMetallurgyBoron Compounds in ChemistryRadiomics and Machine Learning in Medical ImagingArtificial Intelligence in Healthcare and Education