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Enhanced Down-Conversion Emission, High-Level Security, and Advanced Latent Fingerprint Visualization in La<sub>2</sub>Zr<sub>2</sub>O<sub>7</sub>:Er<sup>3+</sup> Nanophosphor through Surface Modification and Deep Learning Analysis

D.R. Lavanya, B.R. Radha Krushna, K. Manjunatha, Bing-Li Lyu, Hsin‐Hao Chiu, Wei-Che Lo, Ming-Kang Ho, Tsu-En Hsu, Sheng Yun Wu, S.C. Sharma, Balanehru Subramanian, J. Malleshappa, Chivukula Srikanth, H. Nagabhushana

2024ACS Applied Optical Materials17 citationsDOIOpen Access PDF

Abstract

High Resolution Image Download MS PowerPoint Slide This study explores surface modifications on Er 3+ -activated La 2 Zr 2 O 7 nanophosphors (NPs) through solution combustion, revealing a narrower band gap (3.1 eV) in surface-modified NPs. Under UV excitation (378 nm), these nanophosphors emit green light at 550 nm, notably enhanced by oleic acid (OA) modification, offering the potential for white light-emitting diode applications. Due to enhanced energy transfer processes, OA-modified NPs show 98.6% color purity and improved quantum efficiency (68.7%). Additionally, OA-modified NPs exhibit promise for UV-based forensic applications. This research also showcases the YOLOv8 algorithm’s robustness (mAP@50 of 0.78 for bifurcation, 0.72 for ridge-end) in fingerprint detection, aiding forensics. The deep learning method supports feature-matching fingerprint detection and advanced identification techniques. These findings offer insights into nanophosphor modification’s optical impact and advanced fingerprint identification methods, contributing to lighting technology and forensic applications.

Topics & Concepts

Materials scienceVisualizationFingerprint (computing)Surface (topology)CrystallographyComputer scienceChemistryArtificial intelligenceMathematicsGeometryLuminescence Properties of Advanced MaterialsRadiation Detection and Scintillator TechnologiesNuclear materials and radiation effects
Enhanced Down-Conversion Emission, High-Level Security, and Advanced Latent Fingerprint Visualization in La<sub>2</sub>Zr<sub>2</sub>O<sub>7</sub>:Er<sup>3+</sup> Nanophosphor through Surface Modification and Deep Learning Analysis | Litcius