Photo-triggered <i>C</i>-arylation of active-methylene compounds with diazonium salts <i>via</i> an electron donor–acceptor (EDA) complex
Shikha Pandey, Arsala Kamal, Ambuj Kumar Kushwaha, Himanshu Singh, Suresh Kumar Maury, Sundaram Singh
Abstract
-arylation under environmentally conscientious conditions, exhibiting exemplary compatibility with diverse functional groups and yielding numerous compounds. This environmentally sustainable transformation underscores the merits of the procedural simplicity and benign reaction conditions. Notably, all resultant products were judiciously derived from active methylene compounds and diazonium salts through the intermediacy of the EDA complex.
Topics & Concepts
MethyleneChemistryAcceptorElectron acceptorElectronElectron donorDiazonium CompoundsPhotochemistryCombinatorial chemistryPolymer chemistryCatalysisMedicinal chemistryOrganic chemistryPhysicsCondensed matter physicsQuantum mechanicsRadical Photochemical ReactionsCatalytic C–H Functionalization MethodsSulfur-Based Synthesis Techniques