Peptide-based chemical models for lytic polysaccharide monooxygenases
Azza A. Hassoon, Attila Szorcsik, Lívia Fülöp, Ibolya Zita Papp, Nóra V. May, Tamás Gajda
Abstract
The Cu( ii )–HPH-NH 2 and Cu( ii )–HPHPY-NH 2 systems were proved to be relevant functional models of LPMOs, even at neutral pH.
Topics & Concepts
ChemistryDimerMonooxygenaseDisproportionationCatalysisAmideChelationStereochemistryHydroxylationResidue (chemistry)MetalMedicinal chemistryPhotochemistryOrganic chemistryEnzymeCytochrome P450Metal-Catalyzed Oxygenation MechanismsEnzyme-mediated dye degradationMicrobial metabolism and enzyme function