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Variable precipitation behaviors of Laves phases in an ultralight Mg-Li-Zn alloy

Weixin Lou, Hongbo Xie, Xiaobo Zhao, Junyuan Bai, Hehang Zhang, Yi Wang, Xinze Li, Hucheng Pan, Yuping Ren, Gaowu Qin

2021Journal of Magnesium and Alloys33 citationsDOIOpen Access PDF

Abstract

Precipitation habits plays a decisive role in strengthening materials, especially for Mg alloys the non-basal plane precipitation is necessary but very limited. Generally, the precipitates would nucleate and grow up in a specific habit plane owing to the constraint of free-energy minimization of the system. Herein, in an aged ultralight Mg-Li-Zn alloy, we confirmed that the precipitates dominated by C15 Laves structure could form in a variety of habit planes, to generate three forms of strengthening-phases, i.e., precipitate-rod, precipitate-lath, and precipitate-plate. Among which, the precipitate-plates are on basal plane as usually but precipitate-rods/laths are on non-basal plane, and such non-basal precipitates would transform into the basal (Mg, Li)Zn2 Laves structure with prolonged aging. These findings are interesting to understand the precipitation behaviors of multi-domain Laves structures in hexagonal close-packed crystals, and expected to provide a guidance for designing ultralight high-strength Mg-Li based alloys via precipitation hardening on the non-basal planes.

Topics & Concepts

Materials sciencePrecipitationAlloyLathNucleationLaves phasePrecipitation hardeningBasal planeCrystallographyMetallurgyChemical engineeringMicrostructureThermodynamicsIntermetallicChemistryPhysicsMeteorologyMartensiteEngineeringMagnesium Alloys: Properties and ApplicationsAluminum Alloys Composites PropertiesAluminum Alloy Microstructure Properties