Mass Transfer Performance Study for CO2 Absorption into Non-Precipitated Potassium Carbonate Promoted with Glycine Using Packed Absorption Column
Nur Farhana Ajua Mustafa, Azmi Mohd Shariff, Wee Horng Tay, Hairul Nazirah Abdul Halim, Siti Munirah Mhd Yusof
Abstract
The removal of carbon dioxide (CO2) at offshore operation requires an absorption system with an environmentally friendly solvent that can operate at elevated pressure. Potassium carbonate promoted with glycine, PCGLY, is a green solvent that has potential for offshore applications. For high solvent concentrations at elevated pressure, the by-product of CO2 absorption consists of precipitates that increase operational difficulty. Therefore, this study was done to assess the CO2 absorption performance of non-precipitated PCGLY with concentration 15wt%PC+3wt%GLY, which is known to have comparable solubility performance with MDEA. A packed absorption column was used to identify the CO2 removal efficiency, mass transfer coefficient in liquid film, k l a e , and overall volumetric mass transfer coefficient, K G a v . A simplified rate-based model was used to determine k l a e and K G a v based on the experimental data with a maximum MAE value, 0.057. The results showed that liquid flow rates and liquid temperature gives significant effects on the k l a e and K G a v profile, whereas gas flow rate and operating pressure had little effect. The CO2 removal efficiency of PCGLY was found to be 77%, which was only 2% lower than 1.2 kmol/m3 MDEA. K G a v of PCGLY is comparable with MDEA. The absorption process using PCGLY shows potential in the CO2 sweetening process at offshore.