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Spin exchange, electronic correlation, and thermoelectric transport in Rb <sub>2</sub> GeMBr <sub>6</sub> (M = V, Mn, Ni) halide double perovskites from first principles calculations

Mudasir Younis Sofi, Mohd. Shahid Khan, Mohd. Shahid Khan, M. Ajmal Khan, M. Ajmal Khan

2025Journal of Materials Chemistry C13 citationsDOI

Abstract

At 300 K, Rb 2 GeVBr 6 , Rb 2 GeMnBr 6 , and Rb 2 GeNiBr 6 exhibit high thermoelectric figure of merit ( zT ) values of 1.00, 0.99, and 0.98, respectively, underscoring their significant potential for renewable energy applications.

Topics & Concepts

HalideMaterials scienceThermoelectric effectCondensed matter physicsFigure of meritSpin (aerodynamics)Thermoelectric materialsSeebeck coefficientEnergy (signal processing)Electronic structureThermoelectric generatorElectronic band structureRenewable energyPerovskite Materials and ApplicationsHeusler alloys: electronic and magnetic propertiesThermal Expansion and Ionic Conductivity
Spin exchange, electronic correlation, and thermoelectric transport in Rb <sub>2</sub> GeMBr <sub>6</sub> (M = V, Mn, Ni) halide double perovskites from first principles calculations | Litcius