Visible light-mediated syntheses of unsymmetrical methylene-bridged <i>bis</i>-heterocycles <i>via</i> an alkoxy radical relay reaction
Tingting Yuan, Jing Chen, Le Nhan Pham, Sayan Paul, Lorenzo V. White, Jialong Li, Ping Lan, Michelle L. Coote, Martin G. Banwell, Yu‐Tao He
Abstract
Efficient syntheses of unsymmetrical methylene bridged bis-heterocycles have been developed involving light-promoted radical relay reactions.
Topics & Concepts
ChemistryMethyleneRelayAlkoxy groupPhotochemistryRadicalRadical cyclizationVisible spectrumCombinatorial chemistryMedicinal chemistryOrganic chemistryOptoelectronicsQuantum mechanicsAlkylPower (physics)PhysicsRadical Photochemical ReactionsCatalytic C–H Functionalization MethodsSulfur-Based Synthesis Techniques