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Review—Pulse-Electrolysis Protocols in High Temperature Molten Salt Electrochemistry

Mengjun Liu, Handong Jiao, Rui Yuan, Manpeng Lin, Linlin Wang, Ruiyang Sun, Leyang Li, Shuqiang Jiao

2023Journal of The Electrochemical Society10 citationsDOIOpen Access PDF

Abstract

High temperature molten salt electrochemistry (MSE) plays a crucial role in the fields of metallurgy, materials, chemical industry and many other important areas. However, the traditional constant potential or constant current electrolysis has low current efficiency and poor product performance, so researchers often use pulse-electrolysis strategy to address this challenge. In this review, we present a discussion on the application of pulse technology in high temperature MSE. Then, we clarify the influence of key factors in the pulse electrolysis process and the internal mechanism of the influence is analyzed. Finally, we conclude with a perspective on the challenges and development directions of pulse electrolysis in high temperature MSE.

Topics & Concepts

ElectrolysisMolten saltElectrochemistryPulse (music)Current (fluid)Process (computing)Process engineeringMaterials scienceConstant (computer programming)Constant currentChemistryElectrodeMetallurgyComputer scienceElectrical engineeringEngineeringVoltagePhysical chemistryProgramming languageOperating systemElectrolyteMolten salt chemistry and electrochemical processesAdvancements in Solid Oxide Fuel CellsMetal Extraction and Bioleaching