Litcius/Paper detail

Electrochemically enabled (3+2) cycloaddition of unbiased alkenes and <i>β</i>-dicarbonyls

Sharad M. Suryawanshi, Suman Sahoo, Parth S. Shaligram, Narugopal Manna, Ramesh C. Samanta

2024Chemical Communications11 citationsDOI

Abstract

A fluorinated porous carbon electrode and Co-salen catalyst reveal (3+2) cycloaddition of unbiased alkenes and β -dicarbonyls to get inaccessible dihydrofurans. It requires no stabilizing group and works for both cyclic and acyclic β -dicarbonyls.

Topics & Concepts

CycloadditionChemistryCombinatorial chemistryOrganic chemistryCatalysisRadical Photochemical ReactionsOxidative Organic Chemistry ReactionsFluorine in Organic Chemistry