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Intermolecular interaction potential maps from energy decomposition for interpreting reactivity and intermolecular interactions

Amin Kiani, Wentong Zhou, Lawrence M. Wolf

2024Physical Chemistry Chemical Physics9 citationsDOI

Abstract

). The IMIPs are applied to the study of various interactions including cation-π and anion-π interactions, electrophilic and nucleophilic aromatic substitution, Lewis acid activation, π-stacking, endohedral fullerenes, and select organometallics which reveal fundamental insight into the positional preferences and physical origins of the interactions that otherwise would be difficult to uncover through other surface analyses.

Topics & Concepts

Intermolecular forceIntermolecular interactionInteraction energyDecompositionReactivity (psychology)Computational chemistryChemical physicsChemistryMoleculeOrganic chemistryMedicineAlternative medicinePathologyCrystallography and molecular interactionsProtein Structure and DynamicsComputational Drug Discovery Methods
Intermolecular interaction potential maps from energy decomposition for interpreting reactivity and intermolecular interactions | Litcius