Enhancing the quantum yield of singlet oxygen: photocatalytic degradation of mustard gas simulant 2-chloroethyl ethyl sulfide catalyzed by a hybrid of polyhydroxyl aluminum cations and porphyrin anions
Ying Yang, Jianbo Yin, Fangsheng Tao, Yunshan Zhou, Lijuan Zhang, Yuxu Zhong, Yong'an Wang
Abstract
A hybrid Al 13 –TCPP was thoroughly characterized as a prototype of polyoxometalate–porphyrin hybrids for the photocatalytic degradation of the mustard gas simulant 2-chloroethyl ethyl sulfide (CEES).
Topics & Concepts
Singlet oxygenChemistryMethanolCatalysisPorphyrinSolventSulfidePhotocatalysisPhotochemistryInorganic chemistryQuantum yieldNuclear chemistryReaction rate constantOxygenOrganic chemistryKineticsQuantum mechanicsPhysicsFluorescencePolyoxometalates: Synthesis and ApplicationsAdvanced Photocatalysis TechniquesPorphyrin and Phthalocyanine Chemistry