Litcius/Paper detail

Selective C(sp<sup>3</sup>)–H bond aerobic oxidation enabled by a π-conjugated small molecule-oxygen charge transfer state

Panyi Huang, Xu Yanbin, Haijing Song, Jiayin Wang, Jiayang Wang, Jianjun Li, Bin Sun, Can Jin

2024Green Chemistry30 citationsDOI

Abstract

A π-conjugated small molecule-oxygen charge transfer state enables selective C(sp 3 )–H oxidation, avoiding the use of photocatalysts, metals, and redox reagents.

Topics & Concepts

Oxidizing agentAllylic rearrangementAlkeneChemistryConjugated systemCatalysisPhotochemistryOxidation stateOxygenMoleculeOrganic chemistryPolymerOxidative Organic Chemistry ReactionsRadical Photochemical ReactionsCatalytic C–H Functionalization Methods