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Grain-size adjustment in Hf<sub>0.5</sub>Zr<sub>0.5</sub>O<sub>2</sub> ferroelectric film to improve the switching time in Hf<sub>0.5</sub>Zr<sub>0.5</sub>O<sub>2</sub>-based ferroelectric capacitor

Jiyeong Yoon, Yejoo Choi, Changhwan Shin

2023Nanotechnology12 citationsDOIOpen Access PDF

Abstract

Abstract By adjusting the rising time in annealing ferroelectric HfO 2 -based films, the grain size of the film can be controlled. In this study, we found that increasing the rising time from 10 to 30 s at an annealing temperature of 700 °C in N 2 atmosphere resulted in improved ferroelectric switching speed. This is because the larger grain size reduces the internal resistance components, such as the grain bulk resistance and grain boundary resistance, of the HZO film. This in turn lowers the overall equivalent resistance. By minimizing the RC time constants, increasing the grain size plays a key role in improving the polarization switching speed of ferroelectric films.

Topics & Concepts

Materials scienceFerroelectricityGrain sizeAnnealing (glass)Grain boundaryPolarization (electrochemistry)Thin filmSwitching timeCondensed matter physicsAnalytical Chemistry (journal)OptoelectronicsComposite materialNanotechnologyMicrostructureDielectricPhysical chemistryPhysicsChemistryChromatographyFerroelectric and Negative Capacitance DevicesMXene and MAX Phase MaterialsSemiconductor materials and devices
Grain-size adjustment in Hf<sub>0.5</sub>Zr<sub>0.5</sub>O<sub>2</sub> ferroelectric film to improve the switching time in Hf<sub>0.5</sub>Zr<sub>0.5</sub>O<sub>2</sub>-based ferroelectric capacitor | Litcius